Phione can be summoned by finding 50 scales and going to the well to make the sea bell, if used, Phione will be your pokemon.
lol oops, i'll fix it. thanks.
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Go to Bluegum Caves (On route 1), on the top right corner of the cave, is the entrance to Bluegum Underground. But you can only access it later in the game after 6 badges etc.